The new coating, called PEDOT, marks a breakthrough in lithium-ion battery technology since it fully and completely protects each particle of the cathode — inside and out — from reactivity with the electrolyte.
The US Department of Energy's (DOE) Argonne National Laboratory, in collaboration with Hong Kong University of Science and Technology (HKUST), has developed a new particle-level cathode coating for lithium-ion batteries meant to increase their life and safety. The idea, three years in the making, was developed at Argonne in collaboration with HKUST. It was funded by the DOE's Office of Renewable Energy and Energy Efficiency, Vehicle Technologies Office. For more information see the IDTechEx report on Li-ion Batteries 2020-2030.
"This is an incredibly exciting advancement," said Khalil Amine, Argonne distinguished fellow and head of the Technology Development group in the Electrochemical Energy Storage department within Argonne's Chemical Sciences and Engineering division. "This could significantly improve our experience with the devices we've come to rely on."
The initial experiment was conducted in Hong Kong: HKUST had the ideal set-up and was able to carry out the work under the laboratory's specifications. Lithium batteries, used to power everything from electric cars to cell phones and computers, have been using a cathode coating technology for more than 15 years.
But it is not without limitations: It is only a partial coating, one that covers just a small part of the outside of the cathode particle and does not protect the cathode when operating at a high voltage or at high temperature.
The cathodes researchers were studying are metal oxides made of nickel, manganese and cobalt. A cathode charged at high voltage generates oxygen, oxidizing the electrolyte, creating an unwanted film on the cathode and causing energy loss. High temperatures increase the speed of these reactions, compromising the electro-chemical performance of the battery itself.
The new coating, made with a conducting polymer called poly(3,4-ethylenedioxythiophene) (PEDOT), marks a breakthrough in lithium-ion battery technology since it fully and completely protects each particle of the cathode — inside and out — from reactivity with the electrolyte.
PEDOT is applied using Argonne's oxidative chemical vapor deposition technique, which uses gas to ensure the coating is applied to every particle of the cathode, forming a robust skin. The conventional coating slows down lithium diffusion in and out of the cathode particle, decreasing battery efficiency because of poor electronic and ionic conductivity.
By contrast, the new Argonne coating facilitates the transport of lithium ions and electrons in and out of the cathode, boosting battery energy.
Currently, lithium-ion batteries operate at 4.2 V at the cell level. The new coating can help increase the voltage to 4.6 V. This 15 percent difference can lead to a significant cost reduction of the overall battery pack.
"This would increase the driving range of electric cars and boost the battery life of cell phones and laptops, ultimately changing the way we live," Amine said.
Source and top image: Argonne National Laboratory